Hi ecoalex,
you are actually using an old kernel: 2.6.33.7, unless you have specific reason to run this kernel, usually there aren't, update to the most recent kernel, 2.6.38.8-pclos3.
to use mylivecd with that kernel you need to specificy the option
--lzma, because the default compression actually used from mylivecd is not supported from that old kernel.
About partitions and umount: you don't need to execute mylivecd from a terminal console, you only need to log out from the current user and then log in as
root, still using the graphics interface.
open a console, and from there copy & paste the following commands:
umount -a
verify what partitions remain mounted, (all partitions somewhat in use will and must remain mounted), using the command:
df -h
the max size you backup using mylivecd is around 10/11 Gb, not more.
I noticed you have a separate /tmp, please note that some area in /tmp is actually used when running mylivecd.
Also, if you are using a separate /boot, take care to not unmount that partition, or remount it, because it's vital for
a bootable liveCD iso.
AS