That is not a command, it is a path to a virtual file meant to be read as a text file, type the following command on the terminal to see what it contains "cat /proc/sys/net/core/rmem_max"
"/proc" is a virtual file system meant to provide runtime information of the system and running processes in a form that can be accessed as if the information is contained in regular text files.
what exactly is the problem you are trying to solve?