i was thinking on a similar procedure, i believe that it can't be done on one single step, or maybe there is a tool doing it we don't know we have?
another option would be to copy everything from one disc to the other and then the other, copy it to the first one, this process shouldn't take too much time, if not much changes happened
still, it is a bit if a dangerous task, because you don't have a central hard disk, so you don't have a plan b if one of the disks fails while copying, perhaps keep a copy of everything on your home partition could help, if there is space for it