Not sure if it's still the case with Windows 7 (what I do know about Win7, is it will want ti create 2 primary partitions for itself), but previous Windows preferred to be installed first, and on the first primary partition.
Can you create a remaster of your install (do you have somewhere to put it, and something to boot from, such as DVD or USB)? If so, you could do that, then install Windows 7 (losing the current PCLOS install), and then re-install PCLOS from your re-master, which would give you your exact environment back.
Be sure to test the re-master as a Live(CD/DVD/USB/whatever), to ensure it is a good one...
You may get other, better, less destructive suggestions, as well...