% is rather meaningless without the disk size being known.
Just19 and Old-Polack, Thank you for your attention.
I agree with both of you

, here is the output from fdisk -l (including two other commands), run as root from KDE 2011.06 LiveCD.
[root@localhost ~]# uname -a
Linux localhost 2.6.38.8-pclos1.bfs #1 SMP PREEMPT Sat Jun 4 04:13:21 CDT 2011 i686 i686 i386 GNU/Linux
[root@localhost ~]# blkid
/dev/loop0: TYPE="squashfs"
[root@localhost ~]# fdisk -l
Disk /dev/sda: 320.1 GB, 320072933376 bytes
255 heads, 63 sectors/track, 38913 cylinders, total 625142448 sectors
Units = sectors of 1 * 512 = 512 bytes
Sector size (logical/physical): 512 bytes / 512 bytes
I/O size (minimum/optimal): 512 bytes / 512 bytes
Disk identifier: 0x00000000
Device Boot Start End Blocks Id System
[root@localhost ~]#
The partitions (calculated per my previous post) would be:
Device Boot GB System
/dev/sda1 * 96 HPFS/NTFS
/dev/sda2 6 Swap (per memory)
/dev/sda3 96 PCLOS (/ and /home)
/dev/sda4 122 Extended (for future use) <-rounded up
Correct me if I am wrong, but I think 96GB is still "excessive" for an OS.

I also think 6GB is excessive for swap, as that machine has 2GB of RAM, expandable to 4GB, if I recall correctly (IIRC?).

More detailed specs will be available as soon as I boot the machine again with the LiveCD (probably tonight or tomorrow morning).
In the meantime, I suggest:
Device Boot GB System
/dev/sda1 * 50 HPFS/NTFS <-entire HDD on their previous machine was 40GB

/dev/sda2 4 Swap (per memory - as currently configured)
/dev/sda3 50 PCLOS (/ and /home)
/dev/sda4 216 Extended
/dev/sda5 50 HPFS/NTFS (backup document storage)
I intend to format and label the partitions prior to installing any OS.
From reading other posts on dual booting with various versions of Windows, I believe I should install XP first on sda1.
When I install PCLOS KDE on sda3, I will remove the check marks for formatting, so that the files are copied from the LiveCD without reformatting the partition.
One of the last steps during installation of PCLOS should automatically detect the XP installation and add it to the boot menu, if I understand the process correctly.

Beyond the remaining facts concerning the machine itself, what am I missing so far?

Again, thank you for your attention and knowledge.

More info will be made available as I have it.
Ideally the next post will be from the machine as I am working on it.

Regards,
Darryl
Personally, I would go with this;
/dev/sda1 * 50 HPFS/NTFS Windows installation
/dev/sda2 50 HPFS/NTFS (backup document storage)
/dev/sda3 4 Swap (per memory - as currently configured)
/dev/sda4 216 Extended
/dev/sda5 20 ext4 PCLOS
/ /dev/sda6 100 ext4 PCLOS
/home <-- Assumes two users with separate login desktops.The rest unpartitioned for the moment, to be partitioned when there is need and sized to fit the need.
or
better, this;
/dev/sda1 * 50 HPFS/NTFS Windows installation
/dev/sda2 50 HPFS/NTFS (backup document storage)
/dev/sda3 4 Swap (per memory - as currently configured)
/dev/sda4 216 Extended
/dev/sda5 30 ext4 PCLOS
/ with
/home included
/dev/sda6 50 ext4 PCLOS data partition mounted as
/home/<user>/Documents./dev/sda7 50 ext4 PCLOS data partition for 2nd user mounted as
/home/<user2>/Documents.
The rest unpartitioned for the moment, to be partitioned when there is need and sized to fit the need.